630551

(2-Ethylhexyl)magnesium bromide solution

1.0 M in diethyl ether

• Fórmula empírica (notación de Hill): C₈H₁₇BrMg
• Número de CAS: 90224-21-8
• Peso molecular: 217.43
• MDL number: MFCD02260220
• UNSPSC Code: 12352103
• PubChem Substance ID: 24882304
• NACRES: NA.22

Propiedades

• reaction suitability: reaction type: Grignard Reaction
• Quality Level: 200
• concentration: 1.0 M in diethyl ether
• density: 0.863 g/mL at 25 °C
• SMILES string: CCCCC(CC)C[Mg]Br
• InChI: 1S/C8H17.BrH.Mg/c1-4-6-7-8(3)5-2;;/h8H,3-7H2,1-2H3;1H;/q;;+1/p-1
• InChI key: NDCJRLBSQQDNOO-UHFFFAOYSA-M

Descripción

Application

(2-Ethylhexyl)magnesium bromide (Grignard reagent) can be used in the synthesis of:       

• 3-ethyl-N,N-dimethyl-1-(pyridin-2-yl)heptan-1-amine, a pyridyl amine ligand, which is used in the polymerization of olefins.   
•  Diphenylbis(2-ethylhexyl) germane from diphenylgermanium dichloride by Grignard addition reaction.       
• Dichloro (dodecyl) 2-ethylhexylsilane, a key intermediate that is used in the preparation of silafluorene-based copolymers.

Información de seguridad

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H302,H314,H336
• pcodes: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• target_organs: Respiratory system
• supp_hazards: EUH014,EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: -13.0 °F - closed cup
• flash_point_c: -25 °C - closed cup