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Merck

510831

Sigma-Aldrich

Poly(3-octylthiophene-2,5-diyl)

regiorandom

Sinónimos:

P3OT

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About This Item

Fórmula lineal:
(C12H18S)n
Número de CAS:
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.23

mol wt

average Mn 22,000
average Mw 36,600

color

red

mp

198-211 °C

solubility

chloroform, methylene chloride, toluene, and THF: soluble

fluorescence

λex 419 nm; λem 550 nm in chloroform

OPV device performance

ITO/PEDOT:PSS/P3OT:PC61BM (1:2)/LiF/Al

  • Short-circuit current density (Jsc): 5.55 mA/cm2
  • Open-circuit voltage (Voc): 0.5 V
  • Fill Factor (FF): 0.33
  • Power Conversion Efficiency (PCE): 0.91 %

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General description

Poly(3-alkylthiophene)s exhibit thermo- and solvatochromism. Regiorandom poly(3-octylthiophene) shows relatively weak red PL in dilute solution. The emission is largely quenched in concentrated solutions and solid thin films.1:1 (head-to-head):(head-to-tail) linkages of regioisomers.
Poly(3-octylthiophene-2,5-diyl) (P3OT) is an alkylthiophene based conductive polymer with high electroluminescence. It is soluble in most of the organic solvents and can be prepared by the electrochemical polymerization of 3-octylthiophene (3OT). It has hydrophobic properties and can be used as a transducer for ion selective electrodes.

Application

P3OT forms a nanocomposite with carbon nanotubes (CNTs) for devising a high performance semiconducting material. It can also be used as a π-conjugating polymer for the fabrication of organic electronic based devices which include polymeric diodes, solar cells and photovoltaic modules.
Conducting polymer.
Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.
Used in organic field-effect transistors and in polymer-based solar cells.

Features and Benefits

Good processability, environmental stability and electroactivity.

Packaging

Packaged in glass bottles

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Visite la Librería de documentos

Semiconducting polymer diodes: Large size, low cost photodetectors with excellent visible-ultraviolet sensitivity
Yu, G and Pakbaz, K and Heeger, AJ
Applied Physics Letters, 64(25), 3422-3424 (1994)
Physical characterizations of semi-conducting conjugated polymer-CNTs nanocomposites
Abu-Abdeen M, et al.
Journal of Polymer Research, 19(3), 9839-9839 (2012)
Light-Emitting Polymers
Pei Q, et al.
Material Matters, 2(3), 26-26 (2007)
Structural analysis of poly (3-alkylthiophene) s
Leclerc M, et al.
Die Makromolekulare Chemie, 190(12), 3105-3116 (1989)
Single-wall carbon nanotube/conjugated polymer photovoltaic devices
Kymakis E and Amaratunga G
Applied Physics Letters, 80(1), 112-114 (2002)

Artículos

Intrinsically stretchable active layers for organic field-effect transistors (OFET) are discussed. Polymer structural modification & post-polymerization modifications are 2 methods to achieve this.

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