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Merck

491748

Sigma-Aldrich

4-(Bromomethyl)pyridine hydrobromide

97%

Sinónimos:

(4-Pyridyl)methyl bromide hydrobromide, 4-(Bromomethyl)pyridine monohydrobromide, 4-Picolyl bromide hydrobromide

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About This Item

Fórmula empírica (notación de Hill):
C6H6BrN · HBr
Número de CAS:
Peso molecular:
252.93
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

mp

189-192 °C (lit.)

SMILES string

Br[H].BrCc1ccncc1

InChI

1S/C6H6BrN.BrH/c7-5-6-1-3-8-4-2-6;/h1-4H,5H2;1H

InChI key

VAJUUDUWDNCECT-UHFFFAOYSA-N

General description

4-(Bromomethyl)pyridine hydrobromide is a substituted pyridine. It reacts with 1,2-ethanediamine and 1,3-propanediamine to form the corresponding diamines.

Application

4-(Bromomethyl)pyridine hydrobromide may be used in the preparation of:
  • 3-(4-pyridylmethyl)-2′,3′-di-O-oleyl-5′-O-(4,4′-dimethoxytriphenylmethyl)uridine
  • 3-(4-pyridylmethyl)-3′-O-oleyl-5′-O-(4,4-dimethoxytriphenylmethyl)-thymidine
  • 1,4-bis(N-hexyl-4-pyridinium)butadiene diperchlorate
It may also be used in the preparation of the following benzoxazine derivatives:
  • 2-morpholin-4-yl-7-(pyridin-4-ylmethoxy)-4H-1,3-benzoxazin-4-one
  • 8-methyl-2-morpholin-4-yl-7-(pyridin-4-ylmethoxy)-4H-1,3-benzoxazin-4-one
  • 2-morpholin-4-yl-8-(pyridin-4-ylmethoxy)-4H-1,3-benzoxazin-4-one

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Luca Simeone et al.
Molecular bioSystems, 7(11), 3075-3086 (2011-09-08)
Novel thymidine- or uridine-based nucleolipids, containing one hydrophilic oligo(ethylene glycol) chain and one or two oleic acid residues (called ToThy, HoThy and DoHu), have been synthesized with the aim to develop bio-compatible nanocarriers for drug delivery and/or produce pro-drugs. Microstructural
Photoinduced electron transfer in supramolecular complexes of a p-extended viologen with porphyrin monomer and dimer.
Fukuzumi S, et al.
Royal Society of Chemistry Advances, 2(9), 3741-3747 (2012)
Cristiane F da Costa et al.
Biomedicine & pharmacotherapy = Biomedecine & pharmacotherapie, 63(1), 40-42 (2008-02-12)
We report in this work the preparation and the in vitro antileishmanial activity of a series of long chains N-monoalkylated diamines and two pyridinediamine derivatives. Several compounds, tested for their in vitro antiproliferative activity against Leishmania amazonensis and Leishmania chagasi
Saleh Ihmaid et al.
European journal of medicinal chemistry, 45(11), 4934-4946 (2010-08-31)
A number of new 2-amino-[5, 6, 7 and 8]-O-substituted 1,3-benzoxazines, and 2-amino 8-methyl-7-O-substituted-1,3-benzoxazines were synthesized. Thirty one new compounds were tested for their effect on collagen induced platelet aggregation and it was found that the most active compounds were 8-methyl-2-morpholin-4-yl-7-(pyridin-3-ylmethoxy)-4H-1,3-benzoxazin-4-one

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