411124

Chlorodicyclohexylborane solution

1 M in hexanes

• Sinónimos: Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane
• Fórmula lineal: (C₆H₁₁)₂BCl
• Número de CAS: 36140-19-9
• Peso molecular: 212.57
• Beilstein/REAXYS Number: 3233942
• MDL number: MFCD00191906
• UNSPSC Code: 12352106
• PubChem Substance ID: 24865728
• NACRES: NA.22

Propiedades

• form: liquid
• reaction suitability: reagent type: reductant
• concentration: 1 M in hexanes
• bp: 68-69 °C
• density: 0.752 g/mL at 25 °C
• SMILES string: ClB(C1CCCCC1)C2CCCCC2
• InChI: 1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
• InChI key: PBBOKJIYEZCTEH-UHFFFAOYSA-N

Descripción

Application

Reactant for:

• Aldol addition reactions
• Mukaiyama aldol addition
• Microwave assisted ring closing metathesis reactions
• C-alkylation of aromatic aldimines
• Reversible ketone-ketone aldol reactions
• Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

Información de seguridad

• pictograms: GHS02,GHS08,GHS05,GHS07,GHS09
• signalword: Danger
• hcodes: H225,H250,H304,H314,H336,H361f,H372,H411
• pcodes: P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3
• target_organs: Central nervous system, Nervous system
• Storage Class: 4.2 - Pyrophoric and self-heating hazardous materials
• wgk_germany: WGK 3
• flash_point_f: 10.4 °F - closed cup
• flash_point_c: -12 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter