345105
Ethylmagnesium bromide solution
1.0 M in tert-butyl methyl ether
Sinónimos:
Bromoethylmagnesium
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About This Item
Fórmula lineal:
CH3CH2MgBr
Número de CAS:
Peso molecular:
133.27
Beilstein/REAXYS Number:
3587203
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Productos recomendados
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in tert-butyl methyl ether
density
0.841 g/mL at 25 °C
SMILES string
CC[Mg]Br
InChI
1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key
TWTWFMUQSOFTRN-UHFFFAOYSA-M
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Application
- Solution Structure and Magnesium Deposition Electrochemistry of Mixing Alkylmagnesium Halide with Magnesium Sulfonyl Amide/Glyme Solution: This research explores the electrochemical behavior of ethylmagnesium bromide in mixed solutions for magnesium deposition applications (Egashira & Hiratsuka, 2016).
- Ethyl magnesium bromide as an efficient anionic initiator for controlled polymerization of ε-caprolactone: The article investigates the use of ethylmagnesium bromide as an initiator for the controlled polymerization of ε-caprolactone (Malinová & Brožek, 2014).
- Room temperature electrodeposition of metallic magnesium from ethylmagnesium bromide in tetrahydrofuran and ionic liquid mixtures: This research focuses on the electrodeposition of metallic magnesium using ethylmagnesium bromide in various solvent mixtures (Chen et al., 2015).
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk_germany
WGK 1
flash_point_f
-29.2 °F - closed cup
flash_point_c
-34 °C - closed cup
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M Wältermann et al.
Microbiology (Reading, England), 146 ( Pt 5), 1143-1149 (2000-06-01)
The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for their capability to accumulate storage lipids in the cytoplasm during cultivation under nitrogen-limiting conditions. Acylglycerols were analysed by matrix-associated
Janne E Tønder et al.
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction
R G Xie et al.
Steroids, 55(11), 488-490 (1990-11-01)
The reaction of ethyl magnesium bromide and 17 alpha-ethynylestradiol with formaldehyde in the presence of triethyl phosphate or hexamethylphosphoramide gave the 2- and 4-formyl-17 alpha-ethynylestradiol in high yield. Treatment of the formyl derivatives with an alkaline solution of hydrogen peroxide
T Nishiyama et al.
Chemical & pharmaceutical bulletin, 48(12), 1999-2002 (2001-01-06)
The direct alpha-bromination of various ketones using trifluoromethanesulfonic anhydride and Grignard reagent or magnesium bromide in ether gave the corresponding alpha-bromo ketones in moderate to good yields under mild reaction conditions.
F Turon et al.
Lipids, 37(8), 817-821 (2002-10-10)
An analytical procedure was developed for regiodistribution analysis of TAG using alpha-MAG prepared by an ethyl magnesium bromide deacylation. In the present communication, the deacylation procedure is shown to lead to representative alpha-MAG, allowing the composition of the native TAG
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