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Merck

343706

Sigma-Aldrich

Dichloro(p-cymene)ruthenium(II) dimer

greener alternative

Sinónimos:

(p-Cymene)ruthenium(II) chloride dimer, Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex

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About This Item

Fórmula lineal:
[Ru(p-cymene)Cl2]2
Número de CAS:
Peso molecular:
612.39
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: C-H Activation

greener alternative product characteristics

Catalysis
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Greener Alternative Product

mp

247.0-250.0 °C (dec.) (lit.)

greener alternative category

SMILES string

Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2

InChI

1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4

InChI key

LAXRNWSASWOFOT-UHFFFAOYSA-J

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Dichloro(p-cymene)ruthenium(II) dimer is a saturated 18-electron complex used as a starting material for the synthesis of organometallic complexes.

Application

Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation

pictograms

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signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable


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Carina Sollert et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(14), 5380-5386 (2015-02-18)
The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range of functional groups on both coupling partners, including bromides and
Bin Li et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 10934-10937 (2012-08-15)
The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-containing molecules: N-phenylpyrazole, 2-phenyl-2-oxazoline and benzo[h]quinoline. N-Phenyl-pyrazole, [RuCl(2)(p-cymene)](2)

Artículos

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