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Key Documents

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246352

Sigma-Aldrich

Methyl carbamate

98%

Sinónimos:

Urethylane

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About This Item

Fórmula lineal:
NH2COOCH3
Número de CAS:
598-55-0
Peso molecular:
75.07
EC Number:
209-939-2
MDL number:
MFCD00007964
UNSPSC Code:
12352100
PubChem Substance ID:
24854803
NACRES:
NA.22

Quality Level

100

assay

98%

form

crystals

bp

176-177 °C (lit.)

mp

56-58 °C (lit.)

solubility

alcohol: freely soluble(lit.)
water: freely soluble(lit.)

SMILES string

COC(N)=O

InChI

1S/C2H5NO2/c1-5-2(3)4/h1H3,(H2,3,4)

InChI key

GTCAXTIRRLKXRU-UHFFFAOYSA-N

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Categorías relacionadas

Application

Methyl carbamate was used in the synthesis of protected aminocyclopropanes.

pictograms

Exclamation markHealth hazard
GHS07,GHS08

signalword

Warning

Hazard Classifications

Carc. 2 - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Ammonium carbamate 99%

Sigma-Aldrich

292834

Ammonium carbamate

Dimethylammonium dimethylcarbamate

Sigma-Aldrich

408395

Dimethylammonium dimethylcarbamate

4-Methoxyphenol ReagentPlus®, 99%

Sigma-Aldrich

M18655

4-Methoxyphenol

Urethane analytical standard

Supelco

76607

Urethane

Shingo Ishikawa et al.
Angewandte Chemie (International ed. in English), 52(38), 10060-10063 (2013-08-06)
Easy as 1,2,3: Reaction of methyl carbamate, triethyl orthoformate, and readily available alkenes provides a highly practical preparation of protected aminocyclopropanes. The reaction proceeds with preferential cis addition to alkenes, and cleavage of the methyl carbamate gives the free aminocyclopropanes
John E Casida et al.
Chemico-biological interactions, 203(1), 221-225 (2012-08-29)
The anticholinesterase (antiChE) organophosphorus (OP) and methylcarbamate (MC) insecticides have been used very effectively as contact and systemic plant protectants for seven decades. About 90 of these compounds are still in use - the largest number for any insecticide chemotype
Xusheng Shao et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(43), 17273-17277 (2013-10-11)
The nicotinic acetylcholine (ACh) receptor (nAChR) is the principal insecticide target. Nearly half of the insecticides by number and world market value are neonicotinoids acting as nAChR agonists or organophosphorus (OP) and methylcarbamate (MC) acetylcholinesterase (AChE) inhibitors. There was no
Catharina Wesseling et al.
Occupational and environmental medicine, 67(11), 778-784 (2010-08-28)
Neuropsychiatric disorders and increased suicide rates have been associated with exposure to cholinesterase inhibiting organophosphates. This study examined symptoms of psychological distress, including suicidal ideation, among banana workers in Costa Rica previously exposed to a cholinesterase inhibiting pesticide. 78 workers
P C Chan et al.
Japanese journal of cancer research : Gann, 83(3), 258-263 (1992-03-01)
Short-term and long-term carcinogenicity of methyl carbamate (MCB) was evaluated in F344 rats and B6C3F1 mice. In experiments lasting 6, 12, and 18 months, MCB was given in water by gavage to groups of 10 male and 10 female rats
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