244430
3-Hexyn-1-ol
98%
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About This Item
Fórmula lineal:
C2H5C≡CCH2CH2OH
Número de CAS:
Peso molecular:
98.14
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.454 (lit.)
bp
63-64 °C/12 mmHg (lit.)
density
0.898 g/mL at 25 °C (lit.)
functional group
hydroxyl
SMILES string
CCC#CCCO
InChI
1S/C6H10O/c1-2-3-4-5-6-7/h7H,2,5-6H2,1H3
InChI key
ODEHKVYXWLXRRR-UHFFFAOYSA-N
Categorías relacionadas
General description
The stereoselective hydrogenation of 3-hexyn-1-ol was studied. Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters showed an extraordinary catalytic performance in the selective hydrogenation of 3-hexyn-1-ol.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk_germany
WGK 3
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Alexander Sachse et al.
Dalton transactions (Cambridge, England : 2003), 42(5), 1378-1384 (2012-10-12)
Well-dispersed Pd nanoparticles have been synthesized inside the mesoporosity of a silica monolith featuring hierarchical porosity of homogeneous interconnected macropores (4 microns) and mesopores (11 nm). These monoliths have been implemented as microreactors for selective hydrogenation reactions. Conversion and selectivity
Jules C A A Roelofs et al.
Chemical communications (Cambridge, England), (8)(8), 970-971 (2004-04-08)
Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters, for the first time exclusively supported on the hydrotalcite lateral surface, showed a remarkable catalytic performance in the selective hydrogenation of 3-hexyn-1-ol, which can be ascribed to both the influence of the protecting polymer PVP as well as
Shigeru Tamogami et al.
FEBS letters, 589(3), 390-395 (2015-01-13)
The medicinal herbal plant Achyranthes bidentata (A. bidentata) produces the sweet-odor ester - methyl (E)-2-hexenoate (1) as the major volatile in response to methyl jasmonate (MeJA). Here, we investigated the biosynthetic pathway of methyl (E)-2-hexenoate (1). The common plant precursor
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