234184

Methyl phenylsulfonylacetate

97%

• Sinónimos: Methyl benzenesulfonylacetate
• Fórmula lineal: C₆H₅SO₂CH₂COOCH₃
• Número de CAS: 34097-60-4
• Peso molecular: 214.24
• Beilstein/REAXYS Number: 2051463
• MDL number: MFCD00007555
• UNSPSC Code: 12352100
• PubChem Substance ID: 24854027
• NACRES: NA.22

Propiedades

• assay: 97%
• refractive index: n20/D 1.535 (lit.)
• bp: 165 °C/0.05 mmHg (lit.)
• density: 1.305 g/mL at 20 °C (lit.)
• functional group: ester; sulfone
• SMILES string: COC(=O)CS(=O)(=O)c1ccccc1
• InChI: 1S/C9H10O4S/c1-13-9(10)7-14(11,12)8-5-3-2-4-6-8/h2-6H,7H2,1H3
• InChI key: NLEAIFBNKPYTGN-UHFFFAOYSA-N
• Gene Information: human ... LOC129293(129293)

Descripción

Application

Methyl phenylsulfonylacetate has been used:

• in a key step during the synthesis of (−)-hybridalactone, marine eicosanoid isolated from the red alga Laurencia hybrida
• in dehydrative alkylation of alcohols under modified Mitsunobu conditions followed by desulfonylation using magnesium
• in three step synthesis of 2-(hydroxymethyl)indene

Información de seguridad

• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 172.4 °F - closed cup
• flash_point_c: 78 °C - closed cup
• ppe: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)