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171441

Sigma-Aldrich

Trifluoroiodomethane

99%

Sinónimos:

Iodotrifluoromethane, Perfluoromethyl iodide, Trifluoromethyl iodide

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About This Item

Fórmula empírica (notación de Hill):
CF3I
Número de CAS:
2314-97-8
Peso molecular:
195.91
Beilstein/REAXYS Number:
1732740
EC Number:
219-014-5
MDL number:
MFCD00001060
UNSPSC Code:
12142100
PubChem Substance ID:
24850061
NACRES:
NA.22

Quality Level

100

assay

99%

bp

−22.5 °C (lit.)

mp

<−78 °C (lit.)

SMILES string

FC(F)(F)I

InChI

1S/CF3I/c2-1(3,4)5

InChI key

VPAYJEUHKVESSD-UHFFFAOYSA-N

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Application

Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,ß-unsaturated ketones.

Packaging

Supplied in a Sure/Pac™ cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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Hose adapter, brass

regulator

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Z513539

Aldrich® mini gas regulator, brass body

signalword

Warning

Hazard Classifications

Muta. 2 - Ozone 1 - Press. Gas Compr. Gas

Storage Class

2A - Gases

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
SHBJ8355
BCBR8746V
SHBC3558V
SHBB7146V
34296KK

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D E Dodd et al.
Inhalation toxicology, 11(11), 1041-1055 (1999-11-24)
CF(3)I is being considered by the U.S. Air Force as a replacement for Halon 1301 for fire-extinguishing requirements in unoccupied spaces. The purpose of this study was to determine and evaluate the potential for CF(3)I to produce reproductive toxicity and
C Stefan Lehmann et al.
Faraday discussions, 153, 173-187 (2011-01-01)
The control of multichannel ionic fragmentation dynamics in CF3I is studied by femtosecond pulse shaping and velocity map photoelectron photoion coincidence imaging. When CF3I is photoexcited with femtosecond laser pulses around 540 nm there are two major ions observed in
G Hancock et al.
Physical chemistry chemical physics : PCCP, 9(18), 2234-2239 (2007-05-10)
Frequency modulated diode laser based absorption at 1.315 microm has been used to measure the Doppler lineshapes of the I((2)P(1/2)-(2)P(3/2)) transition in atomic iodine produced from the 266 nm photolysis of both CF(3)I and C(2)F(5)I. Wavelength resolved laser gain is
A Vinegar et al.
Inhalation toxicology, 12(8), 751-763 (2000-07-06)
Most proposed replacements for Halon 1301 as a fire suppressant are halogenated hydrocarbons. The acute toxic endpoint of concern for these agents is cardiac sensitization. An approach is described that links the cardiac endpoint as assessed in dogs to a
Natalia B Shustova et al.
Journal of the American Chemical Society, 128(49), 15793-15798 (2006-12-07)
Reaction of a mixture of insoluble higher fullerenes with CF3I at 500 degrees C produced a single abundant isomer of C74(CF3)12, C76(CF3)12, and C80(CF3)12, two abundant isomers of C78(CF3)12 and C82(CF3)12, and an indeterminant number of isomers of C84(CF3)12. Using
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Artículos

Tetrakis(dimethylamino)ethylene (TDAE)

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)

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