163015

Thallium(III) nitrate trihydrate

• Sinónimos: TTN, Thallium trinitrate
• Fórmula lineal: Tl(NO₃)₃ · 3H₂O
• Número de CAS: 13453-38-8
• Peso molecular: 444.44
• EC Number: 237-325-4
• MDL number: MFCD00149874
• UNSPSC Code: 12161600
• PubChem Substance ID: 24850018
• NACRES: NA.22

Propiedades

• reaction suitability: core: thallium; reagent type: catalyst
• mp: 102-105 °C (lit.)
• SMILES string: O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
• InChI: 1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3
• InChI key: ZCPIKMRXMBJLCP-UHFFFAOYSA-N

Descripción

Application

Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.

Información de seguridad

• pictograms: GHS06,GHS08,GHS09
• signalword: Danger
• hcodes: H300 + H330,H373,H411
• pcodes: P260 - P264 - P271 - P273 - P304 + P340 + P310 - P314
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
• Storage Class: 5.1B - Oxidizing hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable