162841
2-Methyl-1-naphthol
98%
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About This Item
Fórmula lineal:
CH3C10H6OH
Número de CAS:
Peso molecular:
158.20
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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assay
98%
form
solid
mp
64-66 °C (lit.)
storage temp.
−20°C
SMILES string
Cc1ccc2ccccc2c1O
InChI
1S/C11H10O/c1-8-6-7-9-4-2-3-5-10(9)11(8)12/h2-7,12H,1H3
InChI key
SRJCJJKWVSSELL-UHFFFAOYSA-N
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General description
2-Methyl-1-naphthol undergoes oxidation with molecular oxygen to yield 2-methyl-1,4-naphthoquinone. Mechanism of selective oxidation of 2-methyl-1-naphthol with H2O2 catalyzed by titanium single-site catalysts, TiO2-SiO2 aerogel and mesostructured hydrothermally stable titanium-silicate has been investigated by EPR spectroscopic technique.
Application
2-Methyl-1-naphthol was used in selective synthesis of vitamin K3 via liquid-phase oxidation using NbSBA-15 catalyst.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Los clientes también vieron
Oxana A Kholdeeva et al.
The journal of physical chemistry. B, 115(42), 11971-11983 (2011-09-15)
Oxidation of 2-methyl-1-naphthol (MNL) with molecular oxygen proceeds efficiently under mild reaction conditions (3 atm O(2), 60-80 °C) in the absence of any catalyst or sensitizer and produces 2-methyl-1,4-naphthoquinone (MNQ, menadione, or vitamin K(3)) with selectivity up to 80% in
EPR study on the mechanism of H2O2-based oxidation of alkylphenols over titanium single-site catalysts.
Zalomaeva OV, et al.
J. Mol. Catal. A: Chem., 277(1), 185-192 (2007)
M Selvaraj et al.
Dalton transactions (Cambridge, England : 2003), 41(32), 9633-9638 (2012-07-17)
Well hexagonally ordered NbSBA-15 catalysts synthesized by an efficient hydrothermal method were used, for the first time, for the selective synthesis of vitamin K(3) by liquid-phase oxidation of 2-methyl-1-naphthol (2MN1-OH) under various reaction conditions. The recyclable NbSBA-15 catalysts were also
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