157880
S-(Thiobenzoyl)thioglycolic acid
99%
Sinónimos:
(Thiobenzoylthio)acetic acid, Dithiobenzoic acid carboxymethyl ester
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About This Item
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assay
99%
form
solid
mp
125-127 °C (lit.)
solubility
acetone: soluble 25 mg/mL, clear
functional group
carboxylic acid
SMILES string
OC(=O)CSC(=S)c1ccccc1
InChI
1S/C9H8O2S2/c10-8(11)6-13-9(12)7-4-2-1-3-5-7/h1-5H,6H2,(H,10,11)
InChI key
XBEIANFIOZTEDE-UHFFFAOYSA-N
Categorías relacionadas
General description
S-(Thiobenzoyl)thioglycolic acid (TBTGA) also known as (thiobenzoylthio)acetic acid is a reagent used for thiobenzoylation. It participates in the transformation of threonine into β-methylcysteine.
Application
S-(Thiobenzoyl)thioglycolic acid ((thiobenzoylthio)acetic acid) was employed as reversible addition-fragmentation chain transfer (RAFT) agent during the copolymerization of styrene and divinylbenzene. It was also employed as chain-transfer agent for the RAFT polymerizations of styrene, methyl methacrylate and butyl acrylate.
It may be used to synthesize the following:
It may be used to synthesize the following:
- N-Thiobenzoyl-DL-threonine ethyl ester by reacting with DL-threonine.
- Thiobenzoic acid O-esters by reacting with alkoxides.
- N-Thiobenzoylamino acids by reacting with amino acids.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Los clientes también vieron
Methods in Protein Sequence Analysis, 42-44 (2013)
Photochemical transformations. Part XXXI. Photolysis of thiobenzoic acid O-esters. Part II. General methods for the preparation of thiobenzoic acid O-esters.
Journal of the Chemical Society. Perkin Transactions 1, 1571-1574 (1973)
Thiobenzoylation method of protein sequencing: gas chromatography/mass spectrometric detection of 5-acetoxy-2-phenylthiazoles.
Methods in Protein Sequence Analysis, 37-44 (1993)
Copolymerization Kinetics of Styrene and Divinylbenzene in the Presence of S-Thiobenzoyl Thioglycolic Acid as RAFT Agent.
Chemical Engineering & Technology, 33(11), 1893-1899 (2000)
(Thiocarbonyl-a-thio) carboxylic acid derivatives as transfer agents in reversible addition-fragmentation chain-transfer polymerizations.
Journal of Polymer Science Part A: Polymer Chemistry, 40(4), 555-563 (2002)
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