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33506

Sigma-Aldrich

Oxalic acid dihydrate

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5% (manganometric)

Synonym(s):

Ethanedioic acid dihydrate

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About This Item

Linear Formula:
HO2CCO2H · 2H2O
CAS Number:
Molecular Weight:
126.07
Beilstein:
3679436
EC Number:
MDL number:
UNSPSC Code:
12352100
eCl@ss:
39021701
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

Agency

USP/NF
reag. ISO
reag. Ph. Eur.

vapor density

4.4 (vs air)

vapor pressure

<0.01 mmHg ( 20 °C)

Assay

≥99.5% (manganometric)

form

crystals

impurities

foreign organic matter, in accordance
≤0.001% total nitrogen (N)

ign. residue

≤0.01% (as SO4)

mp

104-106 °C (lit.)

anion traces

chloride (Cl-): ≤5 mg/kg
sulfate (SO42-): ≤20 mg/kg

cation traces

Ca: ≤5 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤2 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg
heavy metals: ≤5 ppm (by ICP-OES)

functional group

carboxylic acid

SMILES string

[H]O[H].[H]O[H].OC(=O)C(O)=O

InChI

1S/C2H2O4.2H2O/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);2*1H2

InChI key

GEVPUGOOGXGPIO-UHFFFAOYSA-N

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General description

Oxalic acid dihydrate crystals are monoclinic and exhibit a space group P21/n. Each unit cell contains two molecules. 13C chemical shielding tensors in oxalic acid dihydrate have been evaluated.

Application

Oxalic acid dihydrate has been used to prepare oxalate precursor, which was employed for the synthesis of zinc oxide nanopowders. It may be used to prepare the 0.01M solution of oxalic acid, which was employed in the mobile phase in liquid chromatographic studies.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Journal of Materials Chemistry, 17(2), 181-184 (2007)
13C chemical shielding in oxalic acid, oxalic acid dihydrate, and diammonium oxalate.
Griffin RG, et al.
J. Chem. Phys. , 63(3), 1267-1271 (1975)

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