D62403
1,2-Dichloroethylene, mixture of cis and trans
98%
Synonym(s):
1,2-Dichloroethene, Acetylene dichloride, sym-Dichloroethylene
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vapor pressure
5.32 psi ( 20 °C)
Assay
98%
form
liquid
refractive index
n20/D 1.447 (lit.)
bp
48-60 °C (lit.)
mp
−57 °C (lit.)
density
1.265 g/mL at 25 °C (lit.)
SMILES string
Cl\C=C\Cl
InChI
1S/C2H2Cl2/c3-1-2-4/h1-2H/b2-1+
InChI key
KFUSEUYYWQURPO-OWOJBTEDSA-N
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General description
1,2-Dichloroethylene, also known as acetylene dichloride, is a chlorinated aliphatic hydrocarbon that is commonly used as an extraction solvent and as a chemical intermediate for other chlorinated solvents and compounds.
Application
1,2-Dichloroethylene, mixture of cis and trans can be used as a reactant to synthesize:
- Chloro-enynes from terminal alkynes via Sonogashira coupling.
- Trichloroethyl alkyl ketones by reacting with acyl chlorides via Friedel-Crafts reaction in the presence of aluminum chloride.
- (Ethenediyl)bis[thiazole] via Pd-catalyzed Stille-coupling reaction with 2-(tributylstannyl)thiazole.
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Product No.
Description
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Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point(F)
42.8 °F - closed cup
Flash Point(C)
6 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Chemistry (Weinheim an der Bergstrasse, Germany), 25(2), 649-656 (2018-11-06)
The effects of the molecular structure of thiazole-based polymers on the active layer morphologies and performances of electronic and photovoltaic devices were studied. Thus, thiazole-based conjugated polymers with a novel thiazole-vinylene-thiazole (TzVTz) structure were designed and synthesized. The TzVTz structure
Environmental science & technology, 44(23), 9105-9111 (2010-11-09)
Abiotic and biotic reductive dechlorination with chlorinated ethene dense non-aqueous-phase liquid (DNAPL) source zones can lead to significant fluxes of complete and incomplete transformation products. Accurate assessment of in situ rates of transformation and the potential for product sequestration requires
Chemistry (Weinheim an der Bergstrasse, Germany), 19(13), 4335-4343 (2013-01-22)
Highly functionalised benzofurans have been prepared from ortho-hydroxyphenones and 1,1-dichloroethylene. The key intermediate, a chloromethylene furan, smoothly rearranged into the corresponding benzofuran carbaldehyde under acidic conditions. Some mechanistic investigations have been performed and several biologically active benzofurans have been synthesised.
Water research, 44(7), 2276-2282 (2010-01-19)
The presence of other chloroethenes influences aerobic metabolic biodegradation of cis-1,2-dichloroethene (cDCE). A new metabolically cDCE degrading enrichment culture was identified as also being capable of degrading vinyl chloride (VC), but not 1,1-dichloroethene (1,1DCE), trans-1,2-dichloroethene (tDCE), trichloroethene (TCE), or tetrachloroethene
Water science and technology : a journal of the International Association on Water Pollution Research, 64(9), 1796-1803 (2011-10-25)
Degradation of the lower chlorinated ethenes is crucial to the application of natural attenuation or in situ bioremediation on chlorinated ethene contaminated sites. Recently, within mixtures of several chloroethenes as they can occur in contaminated groundwater inhibiting effects on aerobic
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