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ALD00608

Sigma-Aldrich

Ni(bpy)3Br2

Synonym(s):

Trisbipyridylnickel dibromide

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About This Item

Empirical Formula (Hill Notation):
C30H24Br2N6Ni
Molecular Weight:
687.05
UNSPSC Code:
12352300

form

powder or crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Application

Ni(bpy)3Br2 is a Ni precatalyst shown by the Baran Lab to be an effective catalyst for the electrochemical amination (e-amination) of arly halides with amines.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

Other Notes

Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications

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Yu Kawamata et al.
Journal of the American Chemical Society, 141(15), 6392-6402 (2019-03-25)
C-N cross-coupling is one of the most valuable and widespread transformations in organic synthesis. Largely dominated by Pd- and Cu-based catalytic systems, it has proven to be a staple transformation for those in both academia and industry. The current study

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