ALD00098

3,6-Bis(methoxycarbonyl)-1,2,4,5-tetrazine

• Synonym(s): Dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate
• Empirical Formula (Hill Notation): C₆H₆N₄O₄
• CAS Number: 2166-14-5
• Molecular Weight: 198.14
• MDL number: MFCD00837735
• UNSPSC Code: 12352100
• PubChem Substance ID: 329772587
• NACRES: NA.22

Properties

• form: crystals
• storage temp.: −20°C
• SMILES string: O=C(C1=NN=C(C(OC)=O)N=N1)OC
• InChI: 1S/C6H6N4O4/c1-13-5(11)3-7-9-4(10-8-3)6(12)14-2/h1-2H3
• InChI key: QODPSGGFQFBWME-UHFFFAOYSA-N

Description

Application

Tetrazine has shown to be a versatile building block as a substrate in inverse elecron demand hetero Diels-Alder reactions. The Boger group has reported this powerful approach in the synthesis of alkaloids.

Other Notes

Total Synthesis of Ningalin D

Total Synthesis of Lycogarubin C and Lycogalic Aci

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable