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773638

Sigma-Aldrich

Poly(N,N-dimethylacrylamide), DDMAT terminated

average Mn 10,000, PDI ≤1.1

Synonym(s):

PDMAM, polyDMAM, polydimethylacrylamide methylpropionic acid dodecyltrithiocarbonate

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About This Item

Linear Formula:
HOCOCH(CH3)2(CH2CHCON(CH3)2)nSCS2C12H25
UNSPSC Code:
12352100
NACRES:
NA.23

form

powder

mol wt

average Mn 10,000

mp

>200 °C

PDI

≤1.1

storage temp.

2-8°C

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Poly(N; N-dimethylacrylamide) is generally used in biological applications. Additionally; the alpha-chain end is a functional carboxylic acid (for potential specialty/coupling reactions). DDMAT is especially suited for the polymerization of styrene; acrylate; and acrylamide monomers to make lithographically and biologically important block copolymers. Useful as a chain Transfer Agent (CTA) or a functionalized polymer

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Articles

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Wide range of functional polymers for biomedical applications have been synthesized and structurally characterized. Several classes of polymers including biodegradable polymers, hydrophilic & amphiphilic polymers, and stimuli responsive polymers have been prepared using controlled and directed functionalization via "living" polymerization such as RAFT, ionic and ring opening polymerization. Selected polymers have been studied for their structure-properties relationship. "

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