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Sigma-Aldrich

Vinylferrocene

97%

Synonym(s):

Ethenylferrocene

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About This Item

Empirical Formula (Hill Notation):
C12H12Fe
CAS Number:
1271-51-8
Molecular Weight:
212.07
EC Number:
215-041-1
MDL number:
MFCD00001434
UNSPSC Code:
12161600
PubChem Substance ID:
24857121
NACRES:
NA.22

Assay

97%

form

solid

reaction suitability

core: iron
reagent type: catalyst

bp

80-85 °C/0.2 mmHg (lit.)

mp

51-53 °C (lit.)

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.C=C[C]2[CH][CH][CH][CH]2

InChI

1S/C7H7.C5H5.Fe/c1-2-7-5-3-4-6-7;1-2-4-5-3-1;/h2-6H,1H2;1-5H;

InChI key

LCPVTGDQYVLJHU-UHFFFAOYSA-N

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Application

Synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides.

Pictograms

Flame
GHS02

Signal Word

Danger

Hazard Statements

H228

Precautionary Statements

P210

Hazard Classifications

Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

143.6 °F - closed cup

Flash Point(C)

62 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Atsunori Hiratsuka et al.
Biosensors & bioelectronics, 21(6), 957-964 (2005-11-01)
We propose a new strategy for constructing a mediator-type biosensor as a Bio-MicroElectroMechanical Systems (BioMEMS) application. A vinylferrocene plasma-polymerized film (PPF) was deposited directly onto the surface of an electrode under dry conditions. The resulting redox film was extremely thin
Ceren Kaçar et al.
Analytical and bioanalytical chemistry, 409(11), 2873-2883 (2017-02-12)
Highly sensitive L-lysine enzyme electrodes were constructed by using poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine (PVF/MWCNTs-GEL) and poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine-graphene (PVF/MWCNTs-GEL/GR) composites as sensing interfaces and their performances were evaluated. Lysine oxidase (LO) was immobilized onto the composite modified glassy carbon electrodes (GCE)
Ryoji Kurita et al.
Biosensors & bioelectronics, 20(3), 518-523 (2004-10-21)
This paper proposes a very simple procedure for preparing a biocompatible sensor based on a protein (bovine serum albumin, BSA), enzyme and vinylferrocene (VF) composite membrane modified electrode. The membrane was prepared simply by first casting vinylferrocene and then coating
Joachim Loup et al.
Angewandte Chemie (International ed. in English), 56(45), 14197-14201 (2017-09-19)
Highly enantioselective iron-catalyzed C-H alkylations by inner-sphere C-H activation were accomplished with ample scope. High levels of enantiocontrol proved viable through a novel ligand design that exploits a remote meta-substitution on N-heterocyclic carbenes within a facile ligand-to-ligand H-transfer C-H cleavage.
Tetrahedron, 63, 761-761 (2007)
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