244937

Dichloro(1,5-cyclooctadiene)platinum(II)

• Synonym(s): (1,5-Cyclooctadiene)platinum(II) dichloride, 1,5-Cyclooctadienedichloroplatinum, (1,5-Cyclooctadiene)platinum dichloride, NSC 239486, Pt(COD)Cl₂
• Empirical Formula (Hill Notation): C₈H₁₂Cl₂Pt
• CAS Number: 12080-32-9
• Molecular Weight: 374.16
• EC Number: 235-144-5
• MDL number: MFCD00012413
• UNSPSC Code: 12161600
• PubChem Substance ID: 24854718
• NACRES: NA.22

Properties

• Quality Level: 100
• reaction suitability: core: platinum; reagent type: catalyst
• mp: 285 °C (dec.) (lit.)
• SMILES string: Cl[Pt]Cl.C1CC=CCCC=C1
• InChI: 1S/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
• InChI key: VVAOPCKKNIUEEU-PHFPKPIQSA-L

Description

Application

Catalyst for:

• Hydrogenative cyclization of allenynes
• Stereoselective tandem hydrosilylation-Hiyama coupling reactions
• Amino alkene cyclohydroamination
• Hydrative cyclization reactions
• Direct amination of allylic alcohols under mild conditions

• Potential anticancer agent

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves