243205
Trimethylamine
anhydrous, ≥99%
Synonym(s):
N,N,N-Trimethylamine, N,N-Dimethylmethanamine
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About This Item
Linear Formula:
(CH3)3N
CAS Number:
Molecular Weight:
59.11
Beilstein:
956566
EC Number:
MDL number:
UNSPSC Code:
12142100
PubChem Substance ID:
NACRES:
NA.22
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grade
anhydrous
Quality Level
vapor density
2.09 (vs air)
vapor pressure
13.3 psi ( 21 °C)
Assay
≥99%
autoignition temp.
374 °F
expl. lim.
11.6 %
impurities
≤0.05% ammonia
≤0.05% methylamine
≤0.2% dimethylamine
bp
3-4 °C (lit.)
mp
−117 °C (lit.)
density
0.63 g/mL at 20 °C (lit.)
functional group
amine
storage temp.
2-8°C
SMILES string
CN(C)C
InChI
1S/C3H9N/c1-4(2)3/h1-3H3
InChI key
GETQZCLCWQTVFV-UHFFFAOYSA-N
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Application
Trimethylamine (TMA) has been used in the preparation of poly[9,9′-bis(6′-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), a water-soluble, cationic conjugated polymer used in label-free DNA microarrays. It can also be used to prepare benzyltrimethylammonium chloride, which then reacts with sodium ethoxide to form benzyltrimethylammonium ethoxide. The adsorption of TMA on the gold surface of trimethylsilylated barium nitrate-gold/titanosilicate catalyst acts as a promoter for the propylene epoxidation with oxygen and hydrogen.
Packaging
Supplied in a Sure/Pac™ cylinder and has a 316 stainless steel needle valve with a male 1/4" NPTF outlet thread installed . Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.
Compatible with the following:
Compatible with the following:
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
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Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Gas 1A - Press. Gas Liquefied gas - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
2A - Gases
WGK
WGK 1
Flash Point(F)
19.4 °F - closed cup
Flash Point(C)
-7 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Benzyltrimethylammonium Ethoxide: Ammonium, benzyltrimethyl?, ethoxide
Croxall W J, et al.
Organic Syntheses, 38, 5-5 (2003)
Trimethylamine as a Gas?Phase Promoter: Highly Efficient Epoxidation of Propylene over Supported Gold Catalysts.
Chowdhury B, et al.
Angewandte Chemie (International Edition in English), 45(3), 412-415 (2006)
Bin Liu et al.
Nature protocols, 1(4), 1698-1702 (2007-05-10)
We describe the synthesis of poly[9,9'-bis(6''-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), a cationic, water-soluble conjugated polymer used in label-free DNA microarrays. This polymer was designed to have a maximum absorbance of close to 488 nm, which meets the excitation wavelength of most commercial
E L Barrett et al.
Annual review of microbiology, 39, 131-149 (1985-01-01)
Trimethylamine oxide, which is found in relatively high concentrations in the tissues of marine animals, serves as an electron acceptor in the anaerobic metabolism of a number of bacteria associated primarily with three environments: the marine environment (e.g. Alteromonas and
M Al-Waiz et al.
Clinical pharmacology and therapeutics, 42(5), 588-594 (1987-11-01)
Trimethylamine (TMA) and its N-oxide (TMAO) are normal components of human urine. They are present in the diet and also derived from the enterobacterial metabolism of precursors such as choline. Dietary TMA is almost entirely metabolized to and excreted as
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 243205-100G | 4061825596068 |
| 243205-400G | 4061825596075 |
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