Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

239615

Sigma-Aldrich

4-Methylpyridine

99%

Synonym(s):

4-Picoline, 4-Methylpyridine

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C6H7N
CAS Number:
108-89-4
Molecular Weight:
93.13
Beilstein:
104586
EC Number:
203-626-4
MDL number:
MFCD00006440
UNSPSC Code:
12352100
PubChem Substance ID:
24854384
NACRES:
NA.22

vapor density

3.2 (vs air)

vapor pressure

4 mmHg ( 20 °C)

Assay

99%

autoignition temp.

1000 °F

refractive index

n20/D 1.504 (lit.)

bp

145 °C (lit.)

mp

2.4 °C (lit.)

solubility

alcohol: soluble(lit.)
diethyl ether: soluble(lit.)
water: soluble(lit.)

density

0.957 g/mL at 25 °C (lit.)

SMILES string

Cc1ccncc1

InChI

1S/C6H7N/c1-6-2-4-7-5-3-6/h2-5H,1H3

InChI key

FKNQCJSGGFJEIZ-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

The reaction of 4-methylpyridine with naphthyl tosylate, that occurred on the methyl group, was studied.

Application

4-Methylpyridine was used in the synthesis of mercury (II) metallacycle.

Pictograms

FlameSkull and crossbones
GHS02,GHS06

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

102.2 °F - closed cup

Flash Point(C)

39 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKBG3385V
12921LE
S27469
16124BZ
06618DV

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 1

1 of 1

Iodomethane contains copper as stabilizer, ReagentPlus®, 99.5%

Sigma-Aldrich

289566

Iodomethane

Fenglin Dai et al.
Chemical communications (Cambridge, England), 49(41), 4634-4636 (2013-04-12)
We have discovered that phenyl tosylates can be used to arylate pyridines at the C3-position using a Pd(OAc)2-1,10-phenanthroline catalyst system. We also discovered that the reaction of 4-methylpyridine with naphthyl tosylates occurred on the methyl group instead of at the
Bhaskar Nath et al.
Dalton transactions (Cambridge, England : 2003), 41(23), 7115-7126 (2012-05-09)
A series of linear coordination polymers, metallacycles of cadmium(II) and mercury(II) of flexible carboxylic acid ligands, RCH{3-CH(3)-,5-CH(3)-,6-(-OCH(2)CO(2)H)C(6)H(2)}(2), (when R = C(6)H(5), (H(2)L(1)); 2-NO(2)C(6)H(4)- (H(2)L(2)) and 3-NO(2)C(6)H(4)- (H(2)L(3))) are synthesized and characterized. [CdL(1) (py)(3)](n)·3nH(2)O (py = pyridine) is a linear coordination
Stéphanie Romand et al.
European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 63, 14-21 (2014-07-06)
A capillary isoelectric focusing (cIEF) method was developed for the determination of the ionization constants (pKa) of small molecules. Two approaches used to decrease the electroosmotic flow (EOF) were compared: (i) a hydroxypropylcellulose (HPC) coated capillary in aqueous medium and

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service