Skip to Content
Merck
All Photos(2)

Key Documents

205729

Sigma-Aldrich

Palladium on barium sulfate

greener alternative

extent of labeling: 5 wt. % loading, unreduced

Synonym(s):

Pd/BaSO4, Rosenmund catalyst

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
Pd
MDL number:
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22

Quality Level

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

extent of labeling

5 wt. % loading

greener alternative category

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Palladium on barium sulfate (Pd/BaSO4), also known as Rosenmund catalyst, is used for the decarboxylation of aliphatic esters for further production of biodiesel. It can also be used in hydrogenation reaction. Pd/BaSO4 may be used as a catalyst reservoir for the Stille cross-coupling reaction between iodobenzene and tributylphenyltin.

Other Notes

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Palladium on carbon-catalyzed solvent-free and solid-phase hydrogenation and Suzuki-Miyaura reaction
Monguchi Y, et al.
Tetrahedron, 67(45), 8628-8634 (2011)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service