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Key Documents

8.22335

Sigma-Aldrich

Sodium azide

for synthesis

Synonym(s):

Sodium azide, Hydrazoic azid sodium salt

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About This Item

Empirical Formula (Hill Notation):
N3Na
CAS Number:
26628-22-8
Molecular Weight:
65.01
MDL number:
MFCD00003536
UNSPSC Code:
12352302
EC Index Number:
247-852-1
NACRES:
NA.22

Quality Level

200

potency

27 mg/kg LD50, oral (Rat)

bp

300 °C/1013 hPa (rigorous decomposition)

mp

275 °C (decomposition)

solubility

408 g/L

density

1.85 g/cm3 at 20 °C

storage temp.

15-25°C

InChI

1S/N3.Na/c1-3-2;/q-1;+1

InChI key

PXIPVTKHYLBLMZ-UHFFFAOYSA-N

Application


  • Synthesis of Quinazoline Derivatives: A copper-catalyzed multicomponent domino reaction of sodium azide is used for the synthesis of quinazoline derivatives, relevant to pharmaceutical chemistry (C Xu, FC Jia, ZW Zhou…, The Journal of Organic Chemistry, 2016). Access the study.


Analysis Note

Assay (cerimetric): ≥ 99.0 %
Identity (ICP-OES): passes test

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2 Oral

Target Organs

Brain

Supplementary Hazards

EUH032

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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