905348

Rh₂(R-p-Ph-TPCP)₄

• Synonym(s): Dirhodium tetrakis((S,R)-1-(4-phenyl(phenyl))-2,2-diphenylcyclopropanecarboxylate), Dirhodium tetrakis[(R)-1-(4-phenyl(phenyl))-2,2- diphenylcyclopropane carboxylate], Tetrakis[(R)-1-(4-phenyl(phenyl))-2,2- diphenylcyclopropane carboxylato]dirhodium(II)
• Empirical Formula (Hill Notation): C₁₁₂H₈₄O₈Rh₂
• CAS Number: 1415389-64-8
• Molecular Weight: 1763.67
• UNSPSC Code: 12352101
• NACRES: NA.22

Properties

• form: powder

Description

Application

Rh catalyst developed by the Davies lab used for enantioselective cyclopropanations and C-H functionalization under low catalyst loadings.

Other Notes

Rh₂(R-TPCP)₄-Catalyzed Enantioselective [3+2]-Cycloaddition between Nitrones and Vinyldiazoacetates

Role of Sterically Demanding Chiral Dirhodium Catalysts in Site-Selective C-H Functionalization of Activated Primary C-H Bonds

Rhodium(II)-Catalyzed C-H Functionalization of Electron-Deficient Methyl Groups

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable