Skip to Content
Merck
All Photos(1)

Key Documents

More Documents

798835

Sigma-Aldrich

[Ru(phd)3](PF6)2

Synonym(s):

Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C36H18F12N6O6P2Ru
CAS Number:
184023-77-6
Molecular Weight:
1021.56
UNSPSC Code:
12352300
PubChem Substance ID:
329768673
NACRES:
NA.22

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

SMILES string

F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]

InChI

1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2

InChI key

LGAOGZFZNIEFHF-UHFFFAOYSA-N

Application

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)3](PF6)2 is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

Legal Information

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

related product

Product No.
Description
Pricing

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Related Content

Stahl Group – Professor Product Portal

he Stahl Lab focuses on the development of catalysts and catalytic reactions for selective oxidation of organic molecules, with particular emphasis on aerobic oxidation reactions.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service