720526

Palladium(π-cinnamyl) chloride dimer

97%

• Synonym(s): Bis[cinnamyl palladium(II) chloride], Palladium(1-phenylallyl)chloride dimer, [(Cinnamyl)PdCl]₂, [Pd(1-phenylallyl)Cl]₂
• Empirical Formula (Hill Notation): C₁₈H₁₈Cl₂Pd₂
• CAS Number: 12131-44-1
• Molecular Weight: 518.08
• MDL number: MFCD16621470
• UNSPSC Code: 12352300
• PubChem Substance ID: 329763720
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 97%
• form: solid
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 218-220 °C
• storage temp.: 2-8°C
• SMILES string: Cl[Pd].Cl[Pd].[CH2][CH][CH]c1ccccc1.[CH2][CH][CH]c2ccccc2
• InChI: 1S/2C9H9.2ClH.2Pd/c2*1-2-6-9-7-4-3-5-8-9;;;;/h2*2-8H,1H2;2*1H;;/q;;;;2*+1/p-2
• InChI key: SHWAPUDBEQXXLQ-UHFFFAOYSA-L

Description

Application

Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:

• Ammonia cross-coupling reactions to synthesize arylamines.
• Conversion of aryl triflates to fluorides.

It can also be used as a source of palladium in the asymmetric α-arylation of amides.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable