Skip to Content
Merck
All Photos(2)

Key Documents

634565

Sigma-Aldrich

Lithium perchlorate

greener alternative

battery grade, dry, 99.99% trace metals basis

Synonym(s):

Lithium cloricum, Perchloric acid, lithium salt

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
LiClO4
CAS Number:
Molecular Weight:
106.39
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

Assay

99.99% trace metals basis

form

powder and chunks

reaction suitability

reagent type: oxidant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

236 °C (lit.)

solubility

H2O: 106.4 g/L at 20 °C

application(s)

battery manufacturing

greener alternative category

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

General description

Lithium perchlorate (LiClO4) is a neutral salt with high solubility. LiClO4 finds use as an electrolyte for lithium-sulfur batteries; it has been shown to give rise to the effective inhibition of the chemical polysulfide shuttle which subsequently boosts the columbic efficiency through the charge process.
Lithium percholate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiClO4 can be used as an additive in the preparation of high-performance polyvinylidene fluoride (PVDF) fibrous membranes. It can also be doped with chitosan and starch for the fabrication of supercapacitors.
LiClO4 is used as an electrolyte salt for lithium-sulfur batteries. LiClO4 acts as a catalyst in the solvent free thiolysis of epoxides. It has been used in various organic transformations.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Shuttle inhibitor effect of lithium perchlorate as an electrolyte salt for lithium-sulfur batteries
Kim HS, et al.
J. Appl. Electrochem., 42(2) (2012)
Lithium perchlorate doped plasticized chitosan and starch blend as biodegradable polymer electrolyte for supercapacitors
Sudhakar YN and Selvakumar M
Electrochimica Acta, 78, 398-405 (2012)
Solvent-free thiolysis of epoxides under lithium perchlorate catalysis.
Mojtahedi M, et al.
Monatshefte fur Chemie / Chemical Monthly, 137(4), 455-458 (2006)
Preparation of porous PVDF hollow fibre membrane via a phase inversion method using lithium perchlorate (LiClO4) as an additive
Yeow ML, et al.
Journal of Membrane Science , 258(1-2), 16-22 (2005)
Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave

Articles

Nanomaterials for Energy Storage in Lithium-ion Battery Applications

Increasing fuel costs and concerns about greenhouse gas emissions have spurred the growth in sales of hybrid electric vehicles (HEVs) that carry a battery pack to supplement the performance of the internal combustion engine (ICE).

Dr. Sun reviews the recent advances in solid-state rechargeable batteries and cover the fundamentals of solid electrolytes in solid-state batteries, the theory of ion conduction, and the structures and electrochemical processes of solid-state Li batteries.

Discover more about advancements being made to improve energy density of lithium ion battery materials.

See All

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service