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Key Documents

542318

Sigma-Aldrich

2,4,6-Trimethylphenylboronic acid

≥95%

Synonym(s):

2,4,6-Trimethylbenzeneboronic acid, Mesitylene-2-boronic acid, NSC 157832

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About This Item

Linear Formula:
C6H2(CH3)3B(OH)2
CAS Number:
Molecular Weight:
164.01
Beilstein:
2831927
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥95%

form

powder

mp

115-122 °C (lit.)

SMILES string

Cc1cc(C)c(B(O)O)c(C)c1

InChI

1S/C9H13BO2/c1-6-4-7(2)9(10(11)12)8(3)5-6/h4-5,11-12H,1-3H3

InChI key

BZXQRXJJJUZZAJ-UHFFFAOYSA-N

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General description

Contains varying amounts of anhydride.

Application

Reactant involved in:
  • Cross-coupling with α-bromocarbonyl compounds or 2,6-disubstituted bromoarenes
  • Suzuki-Miyaura coupling for synthesis of biphenyl arsine ligands
  • Addition reactions to naphthyridine N-oxides or β-aryloxyacrylates

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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