416428

2,2′-Methylenebis[(4S)-4-phenyl-2-oxazoline]

97%

• Synonym(s): (S,S)-2,2′-Methylenebis(4-phenyl-2-oxazoline)
• Empirical Formula (Hill Notation): C₁₉H₁₈N₂O₂
• CAS Number: 132098-59-0
• Molecular Weight: 306.36
• Beilstein: 4202633
• MDL number: MFCD00192295
• UNSPSC Code: 12352005
• PubChem Substance ID: 24866074
• NACRES: NA.22

Properties

• Assay: 97%
• form: viscous liquid
• optical activity: [α]20/D ~−90°, c = 1 in ethanol
• refractive index: n20/D 1.586 (lit.)
• bp: 131-134 °C/0.01 mmHg (lit.)
• density: 1.28 g/mL at 25 °C (lit.)
• functional group: ether; phenyl
• SMILES string: C1OC(CC2=N[C@H](CO2)c3ccccc3)=N[C@H]1c4ccccc4
• InChI: 1S/C19H18N2O2/c1-3-7-14(8-4-1)16-12-22-18(20-16)11-19-21-17(13-23-19)15-9-5-2-6-10-15/h1-10,16-17H,11-13H2/t16-,17-/m1/s1
• InChI key: IUFHJPXOLHSJTC-IAGOWNOFSA-N

Description

Application

C₂ symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 230.0 °F - closed cup
• Flash Point(C): 110 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves