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Sigma-Aldrich

Tris(trimethylsilyl)phosphine

95%

Synonym(s):

(P(TMS)3), Tris(trimethylsilyl)phosphane

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About This Item

Linear Formula:
[(CH3)3Si]3P
CAS Number:
15573-38-3
Molecular Weight:
250.54
MDL number:
MFCD00015487
UNSPSC Code:
12161700
PubChem Substance ID:
24860167
NACRES:
NA.22

Quality Level

100

Assay

95%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.502 (lit.)

bp

243-244 °C (lit.)

density

0.863 g/mL at 25 °C (lit.)

functional group

phosphine

storage temp.

2-8°C

SMILES string

C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C9H27PSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3

InChI key

OUMZKMRZMVDEOF-UHFFFAOYSA-N

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Application

Tris(trimethylsilyl)phosphine (P(TMS)3) can be used as a precursor for the syntheses of:
  • Indium phosphide (InP) and indium gallium phosphide (InGaP) nanocrystals, type III-V semiconductors.
  • Chiral TMS-phospholane which can be further used to synthesize various bisphospholane ligands for asymmetric catalysis.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H250,H261,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Pyr. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

Target Organs

Respiratory system

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Light-induced stimulation of neurons via photoactive surfaces offers rich opportunities for the development of therapeutic methods and high-resolution retinal prosthetic devices. Quantum dots serve as an attractive building block for such surfaces, as they can be easily functionalized to match
Microwave-enhanced reaction rates for nanoparticle synthesis.
Gerbec JA, et al.
Journal of the American Chemical Society, 127(45), 15791-15800 (2005)
Synthesis of a new chiral bisphospholane ligand for the Rh (I)-catalyzed enantioselective hydrogenation of isomeric β-acylamido acrylates.
Holz J, et al.
The Journal of Organic Chemistry, 68(5), 1701-1707 (2003)
Formation of high quality InP and InAs nanocrystals in a noncoordinating solvent.
Battaglia D and Peng X
Nano Letters, 2(9), 1027-1030 (2002)
Francesca Pietra et al.
Chemistry of materials : a publication of the American Chemical Society, 29(12), 5192-5199 (2017-07-15)
In this work, we demonstrate that a preferential Ga-for-Zn cation exchange is responsible for the increase in photoluminescence that is observed when gallium oleate is added to InZnP alloy QDs. By exposing InZnP QDs with varying Zn/In ratios to gallium
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