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220418

Sigma-Aldrich

Aluminum isopropoxide

≥98%

Synonym(s):

AIP, Aluminum isopropylate, Aluminum triisopropoxide

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About This Item

Linear Formula:
Al[OCH(CH3)2]3
CAS Number:
555-31-7
Molecular Weight:
204.24
Beilstein:
3910275
EC Number:
209-090-8
MDL number:
MFCD00008870
UNSPSC Code:
12352103
PubChem Substance ID:
24852958
NACRES:
NA.23

Assay

≥98%

form

solid

reaction suitability

core: aluminum
reagent type: catalyst

mp

128-133 °C (lit.)

density

1.035 g/mL at 25 °C (lit.)

SMILES string

CC(C)O[Al](OC(C)C)OC(C)C

InChI

1S/3C3H7O.Al/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3

InChI key

SMZOGRDCAXLAAR-UHFFFAOYSA-N

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General description

Aluminum isopropoxide is a versatile andinexpensive Lewis acid catalyst and dehydrating agent widely used in the fieldof organic transformations, sol-gel processing, and rechargeable batteries.

Application

Aluminum isopropoxide can be used:
  • As a precursor to synthesize alumina nanoparticles and multimetallic oxides via sol-gel processing.
  • As a catalyst for various organic transformations such as Meerwein–Ponndorf–Verley–Oppenauer (MPVO) reactions and ring-opening polymerization of lactides and lactones.
  • As coating material to fabricate electrodes for lithium-ion batteries toenhance cycling stability and performance.

Pictograms

Flame
GHS02

Signal Word

Danger

Hazard Statements

H228

Hazard Classifications

Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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ACS Applied Materials & Interfaces, 12, 38153-38162 (2020)
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