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18086

Sigma-Aldrich

1-Ethyl-3-methylimidazolium methyl sulfate

≥98.0% (HPLC)

Synonym(s):

[EMIM][MS]

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About This Item

Empirical Formula (Hill Notation):
C7H14N2O4S
CAS Number:
516474-01-4
Molecular Weight:
222.26
MDL number:
MFCD08457697
UNSPSC Code:
12352100
PubChem Substance ID:
57647709
NACRES:
NA.22

Quality Level

100

Assay

≥98.0% (HPLC)

composition

carbon, 37.07-38.58%
nitrogen, 12.35-12.85% (as tested by elemental analysis)

impurities

≤0.2% water

SMILES string

COS([O-])(=O)=O.CCn1cc[n+](C)c1

InChI

1S/C6H11N2.CH4O4S/c1-3-8-5-4-7(2)6-8;1-5-6(2,3)4/h4-6H,3H2,1-2H3;1H3,(H,2,3,4)/q+1;/p-1

InChI key

BXSDLSWVIAITRQ-UHFFFAOYSA-M

General description

1-Ethyl-3-methylimidazolium methyl sulfate [EMIM][MS] when added as an eluent modifier to the mobile phase results in better separation of the three positional isomers of benzoic acid by reversed-phase (RP) high-performance liquid chromatography (HPLC).

Application

[EMIM][MS] may be used as a solvent to synthesize gold nanoparticles via reduction of gold(III) chloride trihydrate [HAuCl4.3H2O] using glycerol as a reducing agent.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314 - H335

Hazard Classifications

Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Retention factors and resolutions of amino benzoic acid isomers with some lonic liquids.
Zheng J, et al.
Biotechnology and Bioprocess Engineering: BBE, 11(6), 477-483 (2006)
Anion effect on the shape evolution of gold nanoparticles during seed-induced growth in imidazolium-based ionic liquids
Keul, Heidrun A., et al.
Physical Chemistry Chemical Physics, 13.30, 13572-13578 (2011)
Surface orientation of 1-methyl-, 1-ethyl-, and 1-butyl-3-methylimidazolium methyl sulfate as probed by sum-frequency generation vibrational spectroscopy
Santos, Cherry S., and Steven Baldelli
The Journal of Physical Chemistry B, 111.18, 4715-4723 (2007)
Imidazolium ionic liquids as solvents of pharmaceuticals: Influence on HSA binding and partition coefficient of nimesulide
Azevedo, Ana MO, et al.
International Journal of Pharmaceutics, 443.1, 273-278 (2013)
Effects of ionic liquid on the separation of 2-chlorophenol and 2, 4, 6-trichlorophenol in RP-HPLC
Zheng, J., and K. H. Row
Journal of Chromatographic Science, 47.5, 392-395 (2009)
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