239305
Sodium hypochlorite solution
reagent grade, available chlorine 4.00-4.99 %
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About This Item
Linear Formula:
NaClO
CAS Number:
Molecular Weight:
74.44
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.21
grade:
reagent grade
form:
liquid
Recommended Products
grade
reagent grade
Quality Level
Agency
suitable for SM 4500 - NH3
vapor pressure
17.5 mmHg ( 20 °C)
form
liquid
composition
available chlorine, 4.00-4.99%
reaction suitability
reagent type: oxidant
concentration
4.00-4.99% (chlorine by Na2S2O3, titration)
density
1.097 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Na+].[O-]Cl
InChI
1S/ClO.Na/c1-2;/q-1;+1
InChI key
SUKJFIGYRHOWBL-UHFFFAOYSA-N
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General description
Sodium hypochlorite (NaOCl) is a commonly used reagent in organic synthesis for many oxidation and chlorination reactions.
Application
Sodium hypochlorite solution can be used as an oxidizing agent for the oxidation of:
It can also be used as a reagent in the:
- Primary alcohols to aldehydes or carboxylic acids and secondary alcohols to ketones.
- Aryl aldehydes to the corresponding acids in the presence of a phase-transfer catalyst.
- Ethers to esters by careful pH control (pH range of 8–9.5),
It can also be used as a reagent in the:
- Epoxidation of enones and polycyclic arenes.
- Oxidative degradation reaction
- N-Chlorination of primary and secondary amines
- Enantioselective epoxidation of α, β-unsaturated ketones
- Asymmetric dihydroxylation of olefins in the presence of an osmium catalyst
- Chlorination of allylic carbons in the presence of CeCl3
Features and Benefits
- Readily available reagent
- Easily handled oxidizing agent
- No phase-transfer catalyst is necessary for the oxidation of substrates in the pH range 10–11
- Simplified waste disposal and lower toxicity
Disclaimer
“The product is not intended for use as a biocide under global biocide regulations, including but not limited to US EPA′s Federal Insecticide Fungicide and Rodenticide Act, European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR) and others.”
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2
Storage Class Code
12 - Non Combustible Liquids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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