32203-M

Diethyl ether

≥99.8% (GC), ACS reagent, puriss. p.a., contains BHT as inhibitor, reag. Ph. Eur., reag. ISO, USP/NF

• Synonym(s): Et2O, Ethoxyethane, Ether, Ethyl ether
• Linear Formula: (CH₃CH₂)₂O
• CAS Number: 60-29-7
• Molecular Weight: 74.12
• Beilstein: 1696894
• EC Number: 200-467-2
• MDL number: MFCD00011646
• UNSPSC Code: 12352112
• PubChem Substance ID: 329754098
• NACRES: NA.21

Properties

• product name: Diethyl ether, contains BHT as inhibitor, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.8% (GC)
• grade: ACS reagent; puriss. p.a.
• Quality Level: 200
• Agency: USP/NF; reag. ISO; reag. Ph. Eur.
• vapor density: 2.6 (vs air)
• Assay: ≥99.8% (GC)
• form: liquid
• autoignition temp.: 320 °F
• contains: BHT as inhibitor
• expl. lim.: 36.5 %
• impurities: ≤0.00007% adehydes (as HCHO); ≤0.0002% free acid (as CH₃COOH); ≤0.001% carbonyl compounds (as CO); ≤0.001% non-volatile matter; ≤0.005% acetone (GC); ≤0.02% ethanol (GC); ≤0.3 ppm peroxides (as H₂O₂); 0.03% water (Karl Fischer); 5-8 ppm BHT (GC)
• refractive index: n20/D 1.3530 (lit.)
• bp: 34.6 °C (lit.)
• mp: −116 °C (lit.)
• density: 0.706 g/mL at 25 °C (lit.)
• cation traces: Al: ≤0.5 mg/kg; B: ≤0.02 mg/kg; Ba: ≤0.1 mg/kg; Ca: ≤0.5 mg/kg; Cd: ≤0.05 mg/kg; Co: ≤0.02 mg/kg; Cr: ≤0.02 mg/kg; Cu: ≤0.02 mg/kg; Fe: ≤0.05 mg/kg; Mg: ≤0.1 mg/kg; Mn: ≤0.02 mg/kg; Ni: ≤0.02 mg/kg; Pb: ≤0.05 mg/kg; Sn: ≤0.1 mg/kg; Zn: ≤0.05 mg/kg
• SMILES string: CCOCC
• suitability: passes test for reaction against H₂SO₄
• InChI: 1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3
• InChI key: RTZKZFJDLAIYFH-UHFFFAOYSA-N

Description

General description

Diethyl ether (DEE) is widely employed as solvent for Grignard synthesis. Its efficacy as solvent for formalin-ether (F-E) sedimentation technique has been studied. It has been reported as a hydroboration solvent. DEE is a promising compression-ignition fuel and its energy density is much higher than ethanol. It is also one of the components in a blend used in diesel fuel. It can also be used as alternative of diesel fuel.

Application

Diethyl ether may be employed as solvent for the oxidation of secondary alcohols into ketones. It may be employed as solvent in the preparation of triblock copolymer of PCL-PEG-PCL, acrylated PCL-PEG-PCL and the pentablock copolymer PAE-PCL-PEG-PCL-PAE [PAE = poly(β-amino ester), PEG = poly(ethylene glycol), PCL = poly(ε-caprolactone)].

Safety Information

• Pictograms: GHS02,GHS07
• Signal Word: Danger
• Hazard Statements: H224 - H302 - H336
• Precautionary Statements: P210 - P233 - P240 - P241 - P301 + P312 - P403 + P233
• Hazard Classifications: Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH019 - EUH066
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 1
• Flash Point(F): -40.0 °F
• Flash Point(C): -40.00 °C