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357324

Sigma-Aldrich

Iridium

foil, thickness 0.25 mm, 99.9% trace metals basis

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About This Item

Empirical Formula (Hill Notation):
Ir
CAS Number:
7439-88-5
Molecular Weight:
192.22
MDL number:
MFCD00011062
UNSPSC Code:
12141720
PubChem Substance ID:
24861904
NACRES:
NA.23

Quality Level

100

Assay

99.9% trace metals basis

form

foil

resistivity

4.71 μΩ-cm

thickness

0.25 mm

bp

4130 °C (lit.)

mp

2450 °C (lit.)

density

22.65 g/cm3 (lit.)

SMILES string

[Ir]

InChI

1S/Ir

InChI key

GKOZUEZYRPOHIO-UHFFFAOYSA-N

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Quantity

3.5 g = 25 × 25 mm

Storage Class Code

13 - Non Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKBS1445V
MKBV6448V
01503HJ
04123DJ
03702MH

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Enantioselective iridium-catalyzed hydrogenation of 1- and 3-substituted isoquinolinium salts.
Zhi-Shi Ye et al.
Angewandte Chemie (International ed. in English), 52(13), 3685-3689 (2013-02-21)
Daniel Shiu-Hin Chan et al.
PloS one, 8(3), e60114-e60114 (2013-03-28)
We report herein a novel luminescent iridium(III) complex with two hydrophobic carbon chains as a non-reaction based chemosensor for the detection of Hg(2+) ions in aqueous solution (<0.002% of organic solvent attributed to the probe solution). Upon the addition of
Carl W Liskey et al.
Journal of the American Chemical Society, 135(9), 3375-3378 (2013-02-21)
The borylation of cyclopropanes catalyzed by the combination of (η(6)-mes)IrBpin3 or [Ir(COD)OMe]2 and a phenanthroline derivative is reported. The borylation occurs selectively at the methylene C-H bonds of the cyclopropane ring over methine or methyl C-H bonds. High diasteroselectivities were
Yuyang Zhou et al.
Chemical communications (Cambridge, England), 49(31), 3230-3232 (2013-03-14)
Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as living cell imaging reagents and
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played
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