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335037

Sigma-Aldrich

Dihydridotetrakis(triphenylphosphine)ruthenium(II)

Synonym(s):

Tetrakis(triphenylphosphine)ruthenium dihydride

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About This Item

Linear Formula:
[(C6H5)3P]4RuH2
CAS Number:
19529-00-1
Molecular Weight:
1156.26
MDL number:
MFCD04126429
UNSPSC Code:
12161600
PubChem Substance ID:
24860280
NACRES:
NA.22

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

mp

181-183 °C (lit.)

SMILES string

[RuH2].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12

InChI

1S/4C18H15P.Ru.2H/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h4*1-15H;;;

InChI key

RXFATFKBDIQXLS-UHFFFAOYSA-N

Application

Catalyst for hydration of nitriles, isomerization of alkynes,Knoevenagel reactions and conjugate additions, and transferhydrogenation

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN7773
MKCH0979
MKBW1437V
MKBP9089V
MKBL3682V

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Ma, D.; Lu, X.
Tetrahedron Letters, 30, 843-843 (1989)
Murahashi, S-I.; Sasao, S. et al.
The Journal of Organic Chemistry, 57, 2521-2521 (1992)
Naota, T.; Taki, H. et al.
Journal of the American Chemical Society, 111, 5954-5954 (1989)

Articles

Knoevenagel Condensation Reaction

Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.

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