237906

Phenyl chloroformate

97%

• Synonym(s): Chloroformic acid phenyl ester
• Linear Formula: ClCOOC₆H₅
• CAS Number: 1885-14-9
• Molecular Weight: 156.57
• Beilstein: 606778
• EC Number: 217-547-8
• MDL number: MFCD00000637
• UNSPSC Code: 12352100
• PubChem Substance ID: 24854276
• NACRES: NA.22

Properties

• vapor density: 1 (vs air)
• Quality Level: 100
• vapor pressure: 1.22 psi ( 20 °C); 1.67 psi ( 55 °C)
• Assay: 97%
• form: liquid
• refractive index: n20/D 1.511 (lit.)
• bp: 74-75 °C/13 mmHg (lit.)
• density: 1.248 g/mL at 25 °C (lit.)
• functional group: chloro; phenoxy
• storage temp.: 2-8°C
• SMILES string: ClC(=O)Oc1ccccc1
• InChI: 1S/C7H5ClO2/c8-7(9)10-6-4-2-1-3-5-6/h1-5H
• InChI key: AHWALFGBDFAJAI-UHFFFAOYSA-N

Description

General description

Kinetics of spontaneous hydrolysis of phenyl chloroformate has been studied in water-ethylene glycol, cationic, zwitterionic, nonionic and anionic micellar solutions.

Application

Phenyl chloroformate has been used in the synthesis of poly(2-(phenoxycarbonyloxy)ethylmethacrylate) and phenyl-(4-vinylphenyl)carbonate.

Safety Information

• Pictograms: GHS06,GHS05
• Signal Word: Danger
• Hazard Statements: H290,H302,H314,H330,H335
• Precautionary Statements: P234 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point(F): 156.2 °F - closed cup
• Flash Point(C): 69 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves