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227129

Sigma-Aldrich

Cobalt(II) acetylacetonate

97%

Synonym(s):

2,4-Pentanedione cobalt(II) derivative, Bis(2,4-pentanedionato)cobalt, Co(acac)2, Cobaltous acetylacetonate

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About This Item

Linear Formula:
Co(C5H7O2)2
CAS Number:
14024-48-7
Molecular Weight:
257.15
EC Number:
237-855-6
MDL number:
MFCD00000014
UNSPSC Code:
12352103
PubChem Substance ID:
24853614
NACRES:
NA.23

Assay

97%

form

powder and chunks

reaction suitability

core: cobalt

impurities

≤3% water

mp

165-170 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Co]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Co/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI key

UTYYEGLZLFAFDI-FDGPNNRMSA-L

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Application


  • Cobalt (II)-Catalyzed Isocyanide Insertion Reaction with Amines: Details a synthetic method for forming ureas and azaheterocycles catalyzed by Cobalt(II) acetylacetonate, applicable in pharmaceutical synthesis (Zhu et al., 2014).

  • Cobalt‐Catalyzed C−H Functionalizations by Imidate Assistance: Describes a method using Cobalt(II) acetylacetonate for C-H functionalization, important for organic synthesis and material chemistry (Mei & Ackermann, 2016).

  • Cobalt (II) acetylacetonate covalently anchored onto magnetic mesoporous silica nanospheres: Focuses on its use as a catalyst for epoxidation of olefins, relevant for catalysis research (Li et al., 2015).

Cobalt(II) acetylacetonate can be used:
  • A precursor in the solvothermal synthesis of Co3O4 nanoparticles. These nanoparticles exhibit high electrochemical performance and are used as a potential supercapacitor material due to their excellent capacitance and cycling stability.
  • A precursor in the preparation of Co3O4 nanoparticles via hydrothermal method. The resulting Co3O4 nanoparticles exhibit a highly-uniform mesoporous structure and tunable sizes, making them promising for CO sensing applications.
  • A precursor for the growth of cobalt oxide thin films using Metal-Organic Chemical Vapor Deposition (MOCVD).

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Ferromagnetic FeCo nanocrystals with high coercivity have been synthesized using a reductive decomposition method. The sizes and shapes of the nanocrystals were found to be dependent on reaction parameters such as the surfactant ratio, the precursor concentration and the heating
Hui Liu et al.
Scientific reports, 7(1), 11421-11421 (2017-09-14)
Alloying platinum (Pt) with suitable transition metals is effective way to enhance their catalytic performance for methanol oxidation reaction, and reduce their cost at mean time. Herein, we report our investigation on the synthesis of bimetallic platinum-cobalt (PtCo) alloy nanoparticles
Itziar Galarreta et al.
Nanomaterials (Basel, Switzerland), 8(2) (2018-01-26)
With the aim of studying the influence of synthesis parameters in structural and magnetic properties of cobalt-doped magnetite nanoparticles, Fe3-xCo
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ACS nano, 13(7), 7716-7728 (2019-06-08)
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