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Merck
모든 사진(3)

주요 문서

34869

Sigma-Aldrich

Dimethyl sulfoxide

suitable for HPLC, ≥99.7%

동의어(들):

DMSO

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About This Item

Linear Formula:
(CH3)2SO
CAS Number:
Molecular Weight:
78.13
Beilstein:
506008
EC Number:
MDL number:
UNSPSC 코드:
41116105
PubChem Substance ID:
NACRES:
NA.21
bp:
189 °C (lit.)
vapor pressure:
0.42 mmHg ( 20 °C)

Grade

HPLC grade

Quality Level

vapor density

2.7 (vs air)

vapor pressure

0.42 mmHg ( 20 °C)

분석

≥99.7%

양식

liquid

autoignition temp.

573 °F

expl. lim.

42 %, 63 °F

기술

HPLC: suitable

불순물

≤0.002% non-volatile matter
≤0.2% water (Karl Fischer)

투과

270 nm, ≥20%
280 nm, ≥50%
300 nm, ≥80%
350 nm, ≥98%

refractive index

n20/D 1.479 (lit.)

bp

189 °C (lit.)

mp

16-19 °C (lit.)

density

1.10 g/mL (lit.)

응용 분야

food and beverages

SMILES string

CS(C)=O

InChI

1S/C2H6OS/c1-4(2)3/h1-2H3

InChI key

IAZDPXIOMUYVGZ-UHFFFAOYSA-N

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일반 설명

Dimethyl sulfoxide (DMSO) is a polar organic solvent. DMSO activated by various electrophiles (oxalyl chloride) has been used to oxidize various alcohols (primary, secondary, allylic, benzylic, hindered and bicyclic). Carbonyl compounds are formed as reaction products. Due to its higher stability, it has been proposed as an alternate solvent for methyl cellosolve for use in ninhydrin reaction.

애플리케이션

Suitable for HPLC, spectrophotometry, environmental testing

주의사항

Supercools easily and remelts slowly at room temperature. Solidified product can be re-liquified by warming to room temperature without detriment to the product.

기타 정보

For information on dimethyl sulfoxide miscibility, please visit the following link:
Dimethyl Sulfoxide Miscibility/Immiscibility Table
Important notice
  • The article number 34869-4X2.5L will be discontinued. Please order the single bottle 34869-2.5L which is physically identical with the same exact specifications.
  • The article number 34869-6X1L will be discontinued. Please order the single bottle 34869-1L which is physically identical with the same exact specifications.

추천 제품

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point (°F)

188.6 °F - closed cup

Flash Point (°C)

87 °C - closed cup


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S HAKOMORI
Journal of biochemistry, 55, 205-208 (1964-02-01)
Oxidation of alcohols by ?activated? dimethyl sulfoxide. A preparative, steric and mechanistic study.
Omura K and Swern D.
Tetrahedron, 34(11), 1651-1660 (1978)
Amino acid analysis: aqueous dimethyl sulfoxide as solvent for the ninhydrin reaction.
S Moore
The Journal of biological chemistry, 243(23), 6281-6283 (1968-12-10)
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