추천 제품
분석
≥95%
형태
crystals
재고 정보
available only in USA
mp
138-139 °C
저장 온도
2-8°C
애플리케이션
1,3-Dimethylimidazoyl-2-ylidene borane is stable NHC-borane developed in the Curran lab. It is a diverse reductant as well as a versatile hydroboration reagent.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
Angewandte Chemie (International ed. in English), 57(32), 10251-10256 (2018-06-22)
1,3-Dimethylimidazol-2-ylidene difluoroborane (NHC-BF2 H) was prepared in a one-pot, two-step reaction from the parent ligated borane (NHC-BH3 ). The derived difluoroboryl radical (NHC-BF2. ) was generated by laser flash photolysis experiments and characterized by UV spectroscopy and rate-constant measurements. It is
Journal of the American Chemical Society, 141(31), 12355-12361 (2019-07-12)
Reactions of readily available alkenyl triflates with N-heterocyclic carbene (NHC)-boranes in the presence of diisopropyl ethyl amine provided about three dozen stable α-NHC-boryl ketones. Isolated yields were typically 40-56% for B-unsubstituted NHC-boranes (NHC-BH3), and somewhat lower for NHC-boranes with B-substituents
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