모든 사진(3)
About This Item
실험식(Hill 표기법):
C36H22F16IrN4O2P
CAS Number:
Molecular Weight:
1069.75
UNSPSC 코드:
12161600
NACRES:
NA.22
추천 제품
![(Ir[dF(CF3)ppy]2(dtbpy))PF6](/deepweb/assets/sigmaaldrich/product/structures/982/913/02dd8ddd-6deb-40a0-ab9b-07b18f1abb09/640/02dd8ddd-6deb-40a0-ab9b-07b18f1abb09.png)
![[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%](/deepweb/assets/sigmaaldrich/product/structures/422/901/e00f3148-fb86-4f94-9e79-21d064c3f327/640/e00f3148-fb86-4f94-9e79-21d064c3f327.png)
![Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6 ≥95%](/deepweb/assets/sigmaaldrich/product/structures/355/743/1aef4eef-372d-4f1d-8904-08df7c4fd417/640/1aef4eef-372d-4f1d-8904-08df7c4fd417.png)
![Ir[dFFppy]2-(4,4′-dCF3bpy)PF6 ≥95%](/deepweb/assets/sigmaaldrich/product/structures/816/772/b116c17c-e6b2-4c95-be64-45a5a851d823/640/b116c17c-e6b2-4c95-be64-45a5a851d823.png)
![[Ir(dF(Me)ppy)2(dtbbpy)]PF6](/deepweb/assets/sigmaaldrich/product/structures/150/099/7c2dfa31-39f4-4cca-aee5-86d4a89fea78/640/7c2dfa31-39f4-4cca-aee5-86d4a89fea78.png)
![[Ir(dFOMeppy)2(dtbbpy)]PF6 ≥95%](/deepweb/assets/sigmaaldrich/product/structures/322/695/c976a02b-e0ec-4b5e-9a54-5324bd63c032/640/c976a02b-e0ec-4b5e-9a54-5324bd63c032.png)
![[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 ≥95%](/deepweb/assets/sigmaaldrich/product/structures/231/079/a5445824-9d4b-4c84-9c5f-f3acbcc75fd4/640/a5445824-9d4b-4c84-9c5f-f3acbcc75fd4.png)
![[Ir(dtbbpy)(ppy)2]PF6](/deepweb/assets/sigmaaldrich/product/structures/158/329/2544d673-d267-4aa1-8f46-2652aad4bfa0/640/2544d673-d267-4aa1-8f46-2652aad4bfa0.png)
![Ir[FCF3(CF3)ppy]2(dtbbpy)PF6](/deepweb/assets/sigmaaldrich/product/structures/378/510/56b6b674-c8d0-4647-8683-91484e1b7543/640/56b6b674-c8d0-4647-8683-91484e1b7543.png)
분석
≥95%
형태
powder or crystals
반응 적합성
reaction type: Photocatalysis
reagent type: catalyst
mp
>300 °C
광촉매 활성화
465 nm
애플리케이션
[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the trifluoromethylation of alkyl bromides.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
David J P Kornfilt et al.
Journal of the American Chemical Society, 141(17), 6853-6858 (2019-04-16)
Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to Csp2 carbon-bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition has
관련 콘텐츠
An organic reaction toolbox provides structure-activity relationships for unique chemical reactions to optimally design and control small molecule synthesis.
Photoredox catalysis utilizes photocatalysts in the presence of visible light to form an array of synthetic transformations including, but not limited to, cross-coupling, C-H functionalization, alkene and arene functionalization, and trifluoromethylation.
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