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Merck
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주요 문서

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911607

Sigma-Aldrich

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6

≥95%

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모든 사진(3)

About This Item

실험식(Hill 표기법):
C36H22F16IrN4O2P
CAS Number:
2307271-69-6
Molecular Weight:
1069.75
MDL number:
MFCD32672288
UNSPSC 코드:
12161600
NACRES:
NA.22

분석

≥95%

양식

powder or crystals

반응 적합성

reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

광촉매 활성화

465 nm

SMILES string

[Ir+](c5c(c(cc(c5)F)F)c6ncc(cc6)OC)c3c(c(cc(c3)F)F)c4ncc(cc4)OC.FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F.F[P-](F)(F)(F)(F)F

InChI

1S/C12H6F6N2.2C12H8F2NO.F6P.Ir/c13-11(14,15)7-1-3-9(19-5-7)10-4-2-8(6-20-10)12(16,17)18;2*1-16-9-3-5-12(15-7-9)10-4-2-8(13)6-11(10)14;1-7(2,3,4,5)6;/h1-6H;2*2-3,5-7H,1H3;;/q;;;-1;+1

InChI key

VCHHFLJLUYSBMX-UHFFFAOYSA-N

관련 카테고리

애플리케이션

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the trifluoromethylation of alkyl bromides.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

기타 정보

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides

관련 제품

제품 번호
설명
가격

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

David J P Kornfilt et al.
Journal of the American Chemical Society, 141(17), 6853-6858 (2019-04-16)
Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to Csp2 carbon-bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition has

관련 콘텐츠

Organic Reaction Toolbox

An organic reaction toolbox provides structure-activity relationships for unique chemical reactions to optimally design and control small molecule synthesis.

Photoredox Catalysis

Photoredox catalysis utilizes photocatalysts in the presence of visible light to form an array of synthetic transformations including, but not limited to, cross-coupling, C-H functionalization, alkene and arene functionalization, and trifluoromethylation.

Global Trade Item Number

SKUGTIN
911607-500MG4061841236719
911607-50MG4061841236726

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