728551

Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride

≥97% (AT)

• 동의어(들): Chloro[N²-[2-(dimethylamino-κN)phenyl]-N¹,N¹-dimethyl-1,2-benzenediaminato-κN¹,κN²]-nickel, Nickamine
• 실험식(Hill 표기법): C₁₆H₂₀ClN₃Ni
• CAS Number: 1033772-47-2
• Molecular Weight: 348.50
• MDL number: MFCD17015253
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329764408
• NACRES: NA.22

속성

• 분석: ≥97% (AT)
• 양식: lumps
• 반응 적합성: core: nickel; reagent type: catalyst
• SMILES string: CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C
• InChI: 1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1
• InChI key: IRLHVNUEEKJBEL-UHFFFAOYSA-M

설명

애플리케이션

Catalyst for:

• Alkyl-alkyl Kumada coupling of secondary alkyl halides
• Direct alkylation of heterocyclic C-H bonds
• Sonogashira coupling of nonactivated alkyl halides
• Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles

Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation

포장

Bottomless glass bottle. Contents are inside inserted fused cone.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable