345857

Tetrabutylammonium chloride hydrate

98%

• 동의어(들): TBAC hydrate
• Linear Formula: (CH₃CH₂CH₂CH₂)₄N(Cl) · xH₂O
• CAS Number: 37451-68-6
• Molecular Weight: 277.92
• Beilstein: 3765327
• EC Number: 214-195-7
• MDL number: MFCD00149970
• UNSPSC 코드: 12352116
• PubChem Substance ID: 24861355
• NACRES: NA.22

속성

• 분석: 98%
• 양식: solid
• mp: 41-44 °C (lit.)
• SMILES string: [Cl-].[N+](CCCC)(CCCC)(CCCC)CCCC.O
• InChI: 1S/C16H36N.ClH.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;/h5-16H2,1-4H3;1H;1H2/q+1;;/p-1
• InChI key: FODWRUPJCKASBN-UHFFFAOYSA-M

설명

애플리케이션

Tetrabutylammonium chloride (TBAC) hydrate has been used as a phase transfer catalyst in the synthesis of fullerenols and in Heck-type palladium-catalyzed vinylation of organic halides in water. TBAC hydrate has also been reported to be a promising candidate for cool energy storage material.

Tetrabutylammonium chloride hydrate can be used:

• As an additive in palladium-catalyzed cross-coupling reaction of heteroaromatic carboxylic acids with aryl bromides.
• To enhance the reactivity of palladium-catalyzed arylation of methyl acrylates.
• In derivatization of bis(spirodienone) calixarene having exocyclic double bonds to its chloro derivative.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves