추천 제품
Quality Level
분석
98%
형태
solid
mp
165-166 °C (lit.)
작용기
chloro
SMILES string
ClC12C[C@H]3C[C@H](C[C@H](C3)C1)C2
InChI
1S/C10H15Cl/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2/t7-,8+,9-,10-
InChI key
OZNXTQSXSHODFR-CHIWXEEVSA-N
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일반 설명
An unusual zwitterionic diradical intermediate complex was generated during the photoinduced electron-transfer substitution reaction between 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass.
애플리케이션
1-Chloroadamantane was employed as precursor for the synthesis of perfluoroadmantane derivatives via aerosol direct fluorination.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
이미 열람한 고객
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Journal of the American Chemical Society, 126(40), 12742-12743 (2004-10-08)
An unusual zwitterionic diradical intermediate complex R*...X-...HR'B*+ is generated during the photoinduced electron-transfer substitution reaction between alkyl halides (RX) and Lewis bases (HR'B). This reaction intermediate was observed for the 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass at 25
Aerosol fluorination of 1-chloroadamantane, 2-chloroadamantane, and methyl 1-adamantylacetate: a novel synthetic approach to 1-and 2-substituted hydryl-, methyl-, and (difluoromethyl-F-adamantanes.
The Journal of Organic Chemistry, 57(17), 4749-4752 (1992)
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