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Solvent-induced invesrsion of enantioselectivity during esterification of 2-phenoxypropionic acid catalyzed by Candida cylindracea lipase has been investigated. Derivatives of 2-phenoxypropionic acid are potential herbicides.
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
Yan He et al.
Journal of pharmaceutical sciences, 95(1), 97-107 (2005-11-30)
The efficiency of a solubilization technique is determined by the physical-chemical properties of the drug. This study investigates the solubilization on two structurally related anticancer drugs, XK-469 and PPA. XK-469 is much less polar than PPA with an intrinsic solubility
Solvent-induced inversion of enantiosflectivity in lipase-catalyzed esterification of 2-phenoxypropionic acids.
Ueji S, et al.
Biotechnology Letters, 14(3), 163-168 (1992)
Manuel A P Segurado et al.
The Journal of organic chemistry, 72(14), 5327-5336 (2007-06-15)
Rate constants were measured for the oxidative chlorodehydrogenation of (R,S)-2-phenoxypropanoic acid and nine ortho-, ten para- and five meta-substituted derivatives using (R,S)-1-chloro-3-methyl-2,6-diphenylpiperidin-4-one (NCP) as chlorinating agent. The kinetics was run in 50% (v/v) aqueous acetic acid acidified with perchloric acid
Lipase-catalyzed production of optically active acids via asymmetric hydrolysis of esters.
Cambou B and Klibanov AM.
Applied Biochemistry and Biotechnology, 9(3), 255-260 (1984)
J Haginaka et al.
Enantiomer, 5(1), 37-45 (2000-04-14)
HPLC chiral stationary phases based on human plasma alpha1-acid glycoprotein (AGP) and partially deglycosylated AGP (pd-AGP) were prepared to investigate the effects of sugar moiety of AGP on chiral discrimination of various solutes. Removal of a sugar moiety of AGP
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