S8032
Sodium azide
BioXtra
Synonym(s):
Hydrazoic acid sodium salt, NSC 3072
About This Item
biological source
synthetic
Quality Level
product line
BioXtra
Assay
99.8%
form
powder or crystals
impurities
≤0.1% Insoluble matter
mp
370-425 °C
solubility
H2O: 1 M at 20 °C, clear, colorless
anion traces
chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.005%
cation traces
Al: ≤0.0005%
Ca: ≤0.005%
Cu: ≤0.0005%
Fe: ≤0.0005%
K: ≤100 mg/kg
Mg: ≤0.001%
Pb: ≤0.001%
Zn: ≤0.0005%
absorption
<1.0 at 276
SMILES string
[Na]N=[N+]=[N-]
InChI
1S/N3.Na/c1-3-2;/q-1;+1
InChI key
PXIPVTKHYLBLMZ-UHFFFAOYSA-N
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Related Categories
Application
Catalyst for:
- Oxidative decarboxylation
- Michael addition reactions
Reagent for synthesis of
- Blue fluorescent copolymers
- Metal phosphonates
- Arenes via aminations
Involved in regioselective synthesis of prianosin B
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2 Oral
Target Organs
Brain
Supplementary Hazards
Storage Class Code
6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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Articles
The chemistry of organoazides is exceedingly rich, since the azide functionality reacts with electrophiles, nucleophiles, and dipolarophiles, with or without the extrusion of dinitrogen. Common place transformation such as Staudinger reductions or ligations, Cu(I)-catalyzed Huisgen cycloadditions (of the “click” reaction family), Curtius or Schmidt rearrangents, nitrene reactions, or imine formation via aza-Wittig reactions all necessitate organoazide precursors or intermediates
Protocols
In Situ Hybridization of Whole-Mount Mouse Embryos with RNA Probes: Hybridization, Washes, and Histochemistry
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