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M4141

Sigma-Aldrich

Methanesulfonic acid solution

4 M (with 0.2% (w/v) tryptamine)

Synonym(s):

Sulfomethane

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About This Item

Linear Formula:
CH3SO3H
CAS Number:
Molecular Weight:
96.11
Beilstein:
1446024
EC Number:
MDL number:
UNSPSC Code:
12352209
PubChem Substance ID:
NACRES:
NA.21

form

liquid

Quality Level

concentration

4 M (with 0.2% (w/v) tryptamine)

storage temp.

2-8°C

SMILES string

CS(O)(=O)=O

InChI

1S/CH4O3S/c1-5(2,3)4/h1H3,(H,2,3,4)

InChI key

AFVFQIVMOAPDHO-UHFFFAOYSA-N

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Application

For complete protein and peptide hydrolysis with tryptophan recovery. After hydrolysis the samples are diluted prior to amino acid analysis.

Packaging

Ampules sealed under argon.

Caution

air sensitive, store under inert conditions

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 2

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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The gas phase reaction between methane sulfonic acid (CH3SO3H; MSA) and the hydroxyl radical (HO), without and with a water molecule, was investigated with DFT-B3LYP and CCSD(T)-F12 methods. For the bare reaction we have found two reaction mechanisms, involving proton
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