65875
3-Methyl-2-benzothiazolinone hydrazone hydrochloride monohydrate
≥99.0% (HPLC)
Synonym(s):
2-Hydrazono-3-methylbenzothiazoline hydrochloride
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About This Item
Empirical Formula (Hill Notation):
C8H9N3S · HCl · H2O
CAS Number:
Molecular Weight:
233.72
Beilstein:
4722243
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥99.0% (HPLC)
form
solid
mp
270-274 °C (dec.)
SMILES string
O.Cl.CN1\C(Sc2ccccc12)=N\N
InChI
1S/C8H9N3S.ClH.H2O/c1-11-6-4-2-3-5-7(6)12-8(11)10-9;;/h2-5H,9H2,1H3;1H;1H2/b10-8-;;
InChI key
IYXXQOGEFHAQGU-GPWRMYTLSA-N
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General description
may contain free HCl
Application
3-Methyl-2-benzothiazolinone hydrazine (MBTH) can be used as a reagent for the spectrophotometric determination of traces of selenium, tellurium, and cyanide in environmental samples.
Other Notes
Reagent for the spectrophotometric determination of aliphatic aldehydes; Reagent for the determination of hexosamines in glycosaminoglycans; Incorporated into a new peroxidase color reaction, Reagent for the spectrophotometric determination of traces of selenium (IV) in environmental samples.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral
Storage Class Code
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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D J Capaldi et al.
Analytical biochemistry, 129(2), 329-336 (1983-03-01)
Hydrogen peroxide in the presence of horseradish peroxidase effects the oxidative coupling of 3-methyl-2-benzothiazolinone hydrazone with its formaldehyde azine to form a tetraazapentamethine dye. The blue chromophore, when formed at pH 3.5 and quenched with acetone or 1 N hydrochloric
Rapid Determination of Tellurium in Organic Compounds by Microwave Plasma-Atomic Emission Spectrometry
Lastovka AV, et al.
Orient. J. Chem., 33(6), 2796-2802 (2017)
Determination of cyanide by an indirect spectrophotometric method using formaldehyde and 3-methyl-2-benzothiazolinone hydrazone
Geetha K and Balasubramanian N
Analytical Letters, 34(14), 2507-2519 (2001)
Quantitation of glycosaminoglycan hexosamine using 3-methyl-2-benzothiazolone hydrazone hydrochloride.
R L Smith et al.
Analytical biochemistry, 98(2), 478-480 (1979-10-01)
J. Bartos et al.
Pure and Applied Chemistry. Chimie Pure Et Appliquee, 51, 1803-1803 (1979)
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