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799661

Sigma-Aldrich

Fe/ppm Pd for Suzuki-Miyaura Cross-Couplings

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About This Item

EC Number:
231-729-4
UNSPSC Code:
12352200

form

powder, crystals or chunks

reaction suitability

core: iron
reaction type: Cross Couplings
reagent type: catalyst

Application

Nanoparticles (NPs) of this material contain parts per million (ppm) levels of Pd. The NPs can catalyze Suzuki-Miyaura (SM) reactions, including cases involving highly challenging reaction partners. Nano micelles are employed to both solubilize and deliver the reaction partners to the Fe/ppm Pd catalyst resulting in C-C bond formation.

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Product No.
Description
Pricing

902292

EvanPhos, ≥95%

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H290 - H302 - H315 - H318

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

Storage Class Code

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Sachin Handa et al.
Science (New York, N.Y.), 349(6252), 1087-1091 (2015-09-05)
Most of today's use of transition metal-catalyzed cross-coupling chemistry relies on expensive quantities of palladium (Pd). Here we report that nanoparticles formed from inexpensive FeCl3 that naturally contains parts-per-million (ppm) levels of Pd can catalyze Suzuki-Miyaura reactions, including cases that
New surfactants for chemistry in water.
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Current opinion in green and sustainable chemistry., 7, 18-22 (2017)
Switching from organic solvents to water at an industrial scale.
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When Does Organic Chemistry Follow Nature?s Lead and ?Make the Switch?.
Lipshutz B H
The Journal of Organic Chemistry, 82(6), 2806-2816 (2017)

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